Investigation of gas content of organic-rich shale:A case study from Lower Permian shale in southern North China Basin,central China     

Wei Dang  Jin-Chuan Zhang  Xuan Tang  Xiao-Liang Wei  Zhong-Ming Li  Cheng-Hu Wang  Qian Chen  Chong Liu 《地学前缘(英文版)》2018,9(2):559-575

Measuring gas content is an essential step in estimating the commerciality of gas reserves. In this study,eight shale core samples from the Mouye-1 well were measured using a homemade patented gas desorption apparatus to determine their gas contents. Due to the air contamination that is introduced into the desorption canister, a mathematical method was devised to correct the gas quantity and quality.Compared to the chemical compositions of desorbed gas, the chemical compositions of residual gas are somewhat different. In residual gas, carbon dioxide and nitrogen record a slight increase, and propane is first observed. This phenomenon may be related to the exposure time during the transportation of shale samples from the drilling site to the laboratory, as well as the differences in the mass, size and adsorptivity of different gas molecules. In addition to a series of conventional methods, including the USBM direct method and the Amoco Curve Fit(ACF) method, which were used here for lost gas content estimation, a Modified Curve Fit(MCF) method, based on the 'bidisperse' diffusion model, was established to estimate lost gas content. By fitting the ACF and MCF models to gas desorption data, we determined that the MCF method could reasonably describe the gas desorption data over the entire time period, whereas the ACF method failed. The failure of the ACF method to describe the gas desorption process may be related to its restrictive assumption of a single pore size within shale samples. In comparison to the indirect method, this study demonstrates that none of the three methods studied in this investigation(USBM, ACF and MCF) could individually estimate the lost gas contents of all shale samples and that the proportion of free gas relative to total gas has a significant effect on the estimation accuracy of the selected method. When the ratio of free gas to total gas is lower than 45%, the USBM method is the best for estimating the lost gas content, whereas when the ratio ranges from 45% to 75% or is more than 75%, the ACF and MCF methods, are the best options respectively.  相似文献   

The evolution of the Huangling uplift and its control on the accumulation and preservation of shale gas     

《China Geology》2018,1(3):346-353

There are plenty of Sinian and Cambrian potential shale gas resources in South China, which is characterized by high thermal evolution degrees, poor drilling performances and only occurs in local areas. Taking the principle “high to find low” is the key issue to achieving a breakthrough in older shale. China Geological Survey drilled in the periphery of the Proterozoic basement, i.e. the Huangling anticline, in the western Hubei, and Hannan paleocontinent in the southern Shanxi. It received high-quality gas-bearing shale with relatively low Ro in the in Lower Cambrian Niutitang formation and Sinian Doushantuo formation. Based on geological conditions of shale gas reservoirs in the Huangling anticline, this paper puts forward the new model named “Control over reservoirs by periphery of basement” about shale gas accumulation, suggesting that the shale deposited in a deepwater continental shelf in the periphery of the basement is characterized by shallow burial, a short burial time, stable tectonics, relatively low thermal evolution degrees, and shale gas reservoirs in a good condition. The shale of the Sinian-Cambrian strata deposited in deepwater continental shelves in the periphery of Chuanzhong paleo-uplift in Sichuan, Hannan paleocontinent in the southern Shanxi, Huangling anticline in western Hubei and Jiangnang-Xuefeng paleo-uplift in Hunan and Guizhou province have good shale gas exploration potential.  相似文献   

温室气体排放的环境库兹涅茨曲线检验与减排路径的冲击动态——基于黑龙江省统计核算数据   总被引：1，自引：0，他引：1  

张滨  吕洁华 《气候变化研究进展》2019,15(1):84-94

基于2001-2015年黑龙江省温室气体排放统计核算数据,对地区GDP与温室气体排放的环境库兹涅茨曲线关系检验呈现倒U型,预期2019年达到理论拐点;通过偏最小二乘回归模型得到4个减排路径的年平均减排效果顺序依次为单位GDP化石能源消费量减少、经济结构调整、人均GDP增长、贸易结构变化;减排路径对应脉冲响应函数的动态冲击效果分别为波动性增排、收敛性减排、发散性减排、转变的排放作用;推动黑龙江省温室气体减排的路径顺序为控制化石能源消费量、优化经济结构、发展低碳经济、调整贸易结构。  相似文献   

塔里木溢流玄武岩火山通道的三维结构及其热成因气体释放   总被引：1，自引：1，他引：0  

王磊  田伟  魏子寒  弓明月  李晓敏 《岩石学报》2018,34(1):75-90

塔里木上奥陶统-志留系沉积地层中广泛发育早二叠世溢流玄武岩的火山通道相岩床-岩墙网络。三维地震数据解释结果显示,这些火山通道以平行围岩地层的岩床和斜切围岩地层的"碟状岩床"为主要特征。在玄武岩喷发过程中,火山通道岩浆的热量可以导致沉积围岩发生热接触变质并将沉积围岩中的有机质转化为"热成因气体"。在塔北英买2井区火山通道烘烤沉积围岩模型基础上,利用有限元热模拟方法确定了该区早二叠世玄武岩喷发时火山通道热烘烤影响范围随时间的变化。基于沉积围岩有机质丰度估算,该区热烘烤成因甲烷释放量可达11.3Gt(即113亿吨)。如果整个塔里木溢流玄武岩省具有与英买2地区相同的释放强度,则塔里木溢流玄武岩省活动期间释放的甲烷总量可达7062.5Gt,必然导致非常显著的环境效应。同时,玄武岩火山通道岩浆引起的热接触变质作用对已存在的油藏具有明显的破坏作用,塔里木盆地古生界总量约8~10Gt的油藏破坏和大量沥青的形成可能与此有关。  相似文献   

隆页2HF页岩气水平井钻井技术研究与实践   总被引：1，自引：1，他引：0       下载免费PDF全文

王彦祺  龙志平 《探矿工程》2018,45(7):30-33

四川盆地周缘蕴藏有大面积常压低丰度海相页岩气,依目前的开发成本,储量难以动用,亟需开展低成本钻井工程工艺技术攻关,盘活该类页岩气资源。中石化华东油气分公司在渝东南武隆地区从钻、测、录、固等方面开展了低成本钻井技术研究。通过分析导致钻井成本高的原因,重点从井身结构优化、井眼轨迹控制优化、钻井工具优选、防漏堵漏措施以及测井、录井、固井工艺优化等方面进行了技术研究与现场实践,试验井隆页2HF井由导眼井与侧钻水平井两部分构成,钻井成本较邻井降低了30%,为武隆地区常压页岩气开发奠定了基础。  相似文献   

3500m岩心钻探装备在油气井勘查中的示范应用     

任启伟  刘凡柏  高鹏举  赵远  伍晓龙 《探矿工程》2018,45(10):57-61

3500 m岩心钻探装备（YDX—6型钻机）是我国自主研发的深部矿产资源勘查技术装备,采用N级口径钻深可达3500 m,其最大特点是采用长油缸钻进和起下钻。本文主要介绍了该钻机在油气井勘查中生产试验情况,同时对矿区地层、钻孔结构、钻进过程、钻进效果、遇到的主要问题及解决办法等进行了介绍。  相似文献   

水射流破碎南海含水合物沉积物数值模拟研究          下载免费PDF全文

潘栋彬  陈晨  杨林  靳成才  李曦桐  刘书源  陈勇  朱江 《探矿工程》2018,45(10):27-31

为研究高压水射流切割、破碎南海天然气水合物储层的过程,采用著名的LS—DYNA显示动力分析有限元程序,对淹没状态下,水射流破碎海底含水合物沉积物过程进行数值模拟研究,研究了不同射流速度对高压水射流作用下含水合物沉积物破碎效果的影响规律。随着射流速度的增大,冲蚀深度逐渐增大,两者呈线性递增关系。含水合物沉积物冲蚀体积是轴向冲蚀与径向冲蚀共同作用的结果,射流速度越大,对含水合物沉积物的轴向与径向冲蚀作用增强,加大了含水合物沉积物冲蚀体积递增速率。  相似文献   

桂北地区罗地1井钻探施工实践   总被引：1，自引：1，他引：0  

秦毅 《探矿工程》2018,45(1):56-59,88

页岩具有较强的水敏性,在页岩气勘查钻进施工中,井内易发生坍塌、剥落造成超径或缩径等井壁失稳现象。罗地1井采用金刚石绳索取心工艺进行钻进,完井井深1501.06 m,岩心采取率、井斜等各项指标均符合地质设计要求。本文主要从罗地1井的钻井设备、井身结构、施工难点等方面进行总结,可为今后页岩气调查井的施工提供参考。  相似文献   

Geological Controls on the CBM Productivity of No.15 Coal Seam of Carboniferous–Permian Taiyuan Formation in Southern Qinshui Basin and Prediction for CBM High-yield Potential Regions     

ZHANG Zheng  QIN Yong  ZHUANG Xinguo  LI Guoqing  LIU Donghai 《《地质学报》英文版》2018,92(6):2310-2332

Coalbed methane (CBM) resources in No.15 coal seam of Taiyuan Formation account for 55% of the total CBM resources in southern Qinshui Basin (SQB), and have a great production potential. This study aims at investigating the CBM production in No.15 coal seam and its influence factors. Based on a series of laboratory experiments and latest exploration and development data from local coal mines and CBM companies, the spatial characteristics of gas production of No.15 coal seam were analyzed and then the influences of seven factors on the gas productivity of this coal seam were discussed, including coal thickness, burial depth, gas content, ratio of critical desorption pressure to original coal reservoir pressure (RCPOP), porosity, permeability, and hydrogeological condition. The influences of hydrological condition on CBM production were analyzed based on the discussions of four aspects: hydrogeochemistry, roof lithology and its distribution, hydrodynamic field of groundwater, and recharge rate of groundwater. Finally, a three-level analytic hierarchy process (AHP) evaluation model was proposed for predicting the CBM potentials of the No.15 coal seam in the SQB. The best prospective target area for CBM production of the No.15 coal seam is predicted to be in the districts of Panzhuang, Chengzhuang and south of Hudi.  相似文献   

Development Phases and Mechanisms of Tectonic Fractures in the Longmaxi Formation Shale of the Dingshan Area in Southeast Sichuan Basin, China     

FAN Cunhui  HE Shun  ZHANG Yu  QIN Qirong  ZHONG Cheng 《《地质学报》英文版》2018,92(6):2351-2366

Shale gas has currently attracted much attention during oil and gas exploration and development. Fractures in shale have an important influence on the enrichment and preservation of shale gas. This work studied the developmental period and formation mechanism of tectonic fractures in the Longmaxi Formation shale in the Dingshan area of ??southeastern Sichuan Basin based on extensive observations of outcrops and cores, rock acoustic emission (Kaiser) experiments, homogenization temperature of fracture fill inclusions, apatite fission track, thermal burial history. The research shows that the fracture types of the Longmaxi Formation include tectonic fractures, diagenetic fractures and horizontal slip fractures. The main types are tectonic high-angle shear and horizontal slip fractures, with small openings, large spacing, low densities, and high degrees of filling. Six dominant directions of the fractures after correction by plane included NWW, nearly SN, NNW, NEE, nearly EW and NW. The analysis of field fracture stage and fracture system of the borehole suggests that the fractures in the Longmaxi Formation could be paired with two sets of plane X-shaped conjugate shear fractures, i.e., profile X-shaped conjugate shear fractures and extension fractures. The combination of qualitative geological analysis and quantitative experimental testing techniques indicates that the tectonic fractures in the Longmaxi Formation have undergone three periods of tectonic movement, namely mid-late Yanshanian movement (82–71.1 Ma), late Yanshanian and middle Himalaya movements (71.1–22.3 Ma), and the late Himalayan movement (22.3–0 Ma). The middle-late period of the Yanshanian movement and end of the Yanshanian movement-middle period of the Himalayan movement were the main fracture-forming periods. The fractures were mostly filled with minerals, such as calcite and siliceous. The homogenization temperature of fracture fill inclusions was high, and the paleo-stress value was large; the tectonic movement from the late to present period was mainly a slight transformation and superposition of existing fractures and tectonic systems. Based on the principle of tectonic analysis and theory of geomechanics, we clarified the mechanism of the fractures in the Longmaxi Formation, and established the genetic model of the Longmaxi Formation. The research on the qualitative and quantitative techniques of the fracture-phase study could be effectively used to analyze the causes of the marine shale gas fractures in the Sichuan Basin. The research findings and results provide important references and technical support for further exploration and development of marine shale gas in South China.  相似文献